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Research Highlight | Materials Science

Rational Synthesis of Superconductors

Magnetically Driven Suppression of Nematic Order in an Iron-based Superconductor

Magnetic order affects the atomic structure. At room temperature, the iron atoms sit on a square lattice, which has four-fold symmetry, but when cooled below the magnetic transition temperature, they distort to form a rectangular lattice, with only two-fold symmetry. This is sometimes called nematic order.” It was thought that this nematic order persists until the material becomes superconducting - until our observation in neutron powder diffraction study on Ba1-xNaxFe2As2. We discovered a phase where the material returns to four-fold C4 symmetry, rather than two-fold C2, close to the onset of super-conductivity. The experimental results provide strong evidence for the validity of an itinerant model of nematic order in the iron-based superconductors, in which the orbital reconstruction of the iron 3d states is a consequence of magnetic interactions induced by Fermi surface nesting. Whether nematic order, or at least strong nematic fluctuations, is a prerequisite for superconductivity is another challenge to address in the future. This research was performed by a collaborative work of EM group and NXS group at MSD.

Related Article

Magnetically-Driven Suppression of Nematic Order in the Iron-Based Superconductors”
S. Avci, O. Chmaissem, J.d Allred, S. Rosenkranz, I. Eremin, A. Chubukov, D. Bugaris, D.Y. Chung, M. Kanatzidis, J.-P. Castellan , J. Schlueter, H. Claus, D. Khalyavin, P. Manuel, A. Daoud-Aladine
Nature Comm., 2014, 5, 3845.