Argonne National Laboratory

David J. Gosztola

Principal Technical Specialist, Nanoscience

Laser-based Spectroscopies

Biography

Research involves the development of laser-based instrumentation for investigating the interaction of light with nanoscale materials and structures.
Expertise in ultrafast photochemistry, interfacial dynamics, electrochemistry, ultrafast laser-based instrumentation design.

Education

  • B.S., Chemistry, Indiana University 
  • Ph.D., Analytical Chemistry, Purdue University
  • PostDoc., Chemistry, Princeton University

Selected Publications

(Selected from 200+ publications)
  • “Axial vs Equatorial: Photocrystallographic Investigation of Intramolecular Charge Transfer (ICT) State Geometry in Conformational Polymorphs of a Donor-Bridge-Acceptor System”, K. Basuroy, J. de J. Velazquez-Garcia, D. Storozhuk, R. Henning, D. J. Gosztola, S. Thekku Veedua, and S. Techert. J. Chem. Phys., 2023, 158, 054304; doi: 10.1063/5.0134792.
  • “In situ X-ray Studies of Growth of Complex Oxides on Graphene by Molecular Beam Epitaxy”, X. Yan, H. Cao, Y. Li, H. Hong, D. J. Gosztola, N. Guisinger, H. Zhou, and D. D. Fong; APL Mater., 2022, 10(9), 091114; doi: 10.1063/5.0101416.
  • “Pulsed Laser Deposition and Structural Evolution of BaF2 Nanolayers in Eu-doped BaF2/Al2O3 Layered Optical Nanocomposite Thin Films”, Y. Jin, C. W. Bond, P. Gómez-Rodriguez, E. Nieto-Pinero, R. L. Leonard, D. J. Gosztola, J. A. Johnson, J. Gonzalo, R. Serna, and A. K. Petford-Long; Thin Solid Films, 2022, 174, 139298; doi: 10.1016/j.tsf.2022.139298.
  • “Triplet Photodynamic and Anti-Stokes Photoluminescence in Donor-Acceptor Dyads with Slip-stacked vs. Co-facial Arrangement”, Y. J. Yun, G. P. Wiederrecht, D. J. Gosztola, B. T. Diroll, and A. J.-L. Ayitou; J. Mater. Chem. C, 2022, 10(8), 7093-7102; doi: 10.1039/D1TC05122A.
  • “Structural Capture of η1-OSO to η2-(OS)O Coordination Isomerism in a New Ruthenium-based SO2 Linkage Photoisomer that Exhibits Single-crystal Optical Actuation”, J. Cole, D. Gosztola, J. Velazquez-Garcia; J. Phys. Chem. C, 2022, 126(13), 6047-6059; doi: 10.1021/acs.jpcc.2c00170.
  • “Synthesis and Photophysics of Phenylene Based Triplet Donor–Acceptor Dyads: ortho vs. para Positional Effect on Intramolecular Triplet Energy Flow”, Y. J. Yun, M. K. Manna, N. Kamatham, J. Li, L. Shuyang, F. Peccati, B. C. Pemberton, G. P. Wiederrecht, D. J. Gosztola, G. Jiménez-Osés, A. Y. Rogachev, and A. J.-L. Ayitou; J. Photochem. Photobiol., 2022, 10, 100112; doi:10.1016/j.jpap.2022.100112
  • “Photometric Sensing of Heavy Metal Ions Using a Naphthoquinodimethyl-bis-thioamide Dye: Selectivity & Photophysics of the Metal Organic Complexes”, S. Maharjan, Y. J. Yun, V, A. Okello, G. P. Wiederrecht, D. J. Gosztola, and A. J.-L. Ayitou; J. Photochem. Photobiol. A, 2022, 424, 113648; doi: 10.1016/j.jphotochem.2021.113648.
  • “Single-crystal Optical Actuation Generated by 100% SO2 Linkage Photoisomerization in a Ruthenium-based Coordination Complex”, J. M. Cole, D. J. Gosztola, J. de J. Velazquez-Garcia, S. Y. Grass Wang, Y.-S. Chen; J. Phys. Chem. C, 2021, 125(36), 20059-20066; doi: 10.1021/acs.jpcc.1c05903.
  • “Ultrafast Studies of Hot-Hole Dynamics in Au/p-GaN Heterostructures“ ‘ G. Tagliabue, J. S. DuChene, M. Abdellah, A. Habib, D. J. Gosztola, Y. Hattori, W.-H. Cheng, K. Zheng, S. E. Canton, R. Sundararaman, J. Sá, and H. A. Atwater; Nat. Mater, 2020, 19(12), 1312–1318; doi: 10.1038/s41563-020-0737-1.
  • “Mechanistic Insight of Photocatalysis using MIL-100(Fe)/TiO2 Composites”, X. He, H. Fang, D. J. Gosztola, Z. Jiang, P. Jena, and W.-N. Wang; ACS Appl. Mater. Interfaces, 2019, 11(13), 12516-12524, doi: 10.1021/acasmi.9b00223.
  • “Ultrathin Transmissive Metasurfaces for Multiwavelength Optics in the Visible”, H. Cai, D. Czaplewski, K. Ogando, A. Martinson, D. Gosztola, L. Stan, and D López; Appl. Phys. Lett., 2019, 114, 071106; doi: 10.1063/1.5082557.
  • “Effects of Chlorine in Ash on the Corrosion Performance of Ni-based Alloys in Simulated Oxy-fuel Environment”, Z. Zeng, K. Natesan, Z. Cai, and D. Gosztola; Energy & Fuels, 2018, 32(10), 10502-10512; doi: 10.1021/acs.energyfuels.8b02233.
  • “Life-time and Line-width of Individual Quantum Dots Interfaced with Graphene”, X. Miao, D. J. Gosztola, A. V. Sumant, and H. Grebel; Nanoscale, 2018, 10, 7040-7046; doi: 10.1039/C8NR01769G
  • “Probing the Impact of Solvation on Photoexcited Spin Crossover Complexes with High-precision X-ray Transient Absorption Spectroscopy”, C. Liu, J. Zhang, L. Lawson Daku, D. Gosztola, S. Canton, and X. Zhang; J. Am. Chem. Soc., 2017, 139(48), 7518–17524; doi: 10.1021/jacs.7b09297.
  • “Anisotropic Scattering of Hot Electrons in an Ultra-Broadband Plasmonic Nanopatch Metasurface”, M. Sykes, J. Stewart, G. Akselrod, X.-T. Kong, Z. Wang, D. J. Gosztola, A. B. F. Martinson, D. Rosenmann, M. H. Mikkelsen, A. O. Govorov, and G. P. Wiederrecht; Nature Comm., 2017, 8, 986; doi: 10.1038/s41467-017-01069-3.
  • “Enhanced Raman Scattering from NCM523 Cathodes Coated with Electrochemically Deposited Gold”, A. Tornheim, V. A. Maroni, M. He, D. J. Gosztola, and Z. Zhang; J. Electrochem. Soc., 2017, 164(13), A3000; doi: 10.1149/2.0461713jes.
  • “Photon Upconversion Using Anti-Aromatic Naphtho-p-quinodimethane as a Light Harvesting Sensitizer”, S. Shokri, G. Wiederrecht, D. Gosztola, and A. Ayitou; J. Phys. Chem. C., 2017, 121(42), 23377, doi: 10.1021/acs.jpcc.7b08373.
  • “Size-Dependent Biexciton Quantum Yields and Carrier Dynamics of Quasi-Two-Dimensional Nanoplatelets”, X. Ma, B. Diroll, I. Fedin, R. Schaller, D. Talapin, S. Gray, G. Wiederrecht, and D. Gosztola; ACS Nano, 2017, 11(9), 9119–9127, doi: 10.1021/acsnano.7b03943
  • “Photon-Induced Selenium Migration in TiSe2”, D. B. Lioi, D. J. Gosztola, G. P. Wiederrecht, and G. Karapetrov; Appl. Phys. Lett., 2017, 110(8), 081901; doi: 10.1063/1.4976745.
  • “Direct Experimental Evidence for Photoinduced Strong-Coupling Polarons in Organolead Halide Perovskite Nanoparticles”, K. Zheng, M. Abdellah, Q. Zhu, Q. Kong, G. Jennings, C. A. Kurtz, M. E. Messing, Y, Niu, D. Gosztola, M. J. Al-Marri, X. Zhang, T. Pullerits, and S. E. Canton; J. Phys. Chem. Lett., 2016, 7(22), 4535-4539; doi: 10.1021/acs.jpclett.6b02046.
  • “Ultrafast Optical Modulation of Second and Third Harmonic Generation from Cut-Disk-Based Metasurfaces”, G. Sartorello, N. A. H. Olivier, G. Wurtz, J. Zhang, W.  Yue, D. J. Gosztola, G. P. Wiederrecht, and A. V. Zayats; ACS Photonics, 2016, 3(8), 1517-1522; doi: 10.1021/acsphotonics.6b00108.
  • “Nano-Optical Imaging of WSe2 Waveguide Modes Revealing Light-Exciton Interactions, Z. Fei, M. Scott, D. J. Gosztola, J. J. Foley, H. Wen, Y. Sun, R. D. Schaller, J. R. Guest, S. K. Gray, G. P. Wiederrecht, W. Bao, and X. Xu; Phys. Rev. B., 2016, 94(8), 081402(R); doi: 10.1103/PhysRevB.94.081402
  • “Photoexcited Carrier Dynamics of In2S3 Thin Films”, R. McCarthy, R. Schaller, D. Gosztola, G. Wiederrecht, and A. Martinson; J. Phys. Chem. Lett., 2015, 6, 2554–2561.
  • “Visualizing the Nonequilibrium Dynamics of Photoinduced Intramolecular Electron Transfer with Femtosecond X-ray Pulses”, S. E. Canton, K. S. Kjær, G. Vankó, T. B. van Driel, S. Adachi, A. Bordage, C. Bressler, P. Chabera, M. Christensen, A. O. Dohn, A. Galler, W. Gawelda, D. Gosztola, et al.; Nature Commun., 2015, 6, 6359.

Patents

  • No. 10164188 Polymer-Hybrid Electro-Optic Devices and Method of Fabricating Polymer-Hybrid Electro-Optic Devices, L. E. Ocola, D. J. Gosztola, and A. I. Yanguas-Gil
  • No. 9548677 and 8922094 Microelectromechanical (MEMS) Manipulators for Controlling Nanoparticle Coupling Interactions, D. Lopez, G. Wiederrecht, D. Gosztola, and D. Mancini
  • No. 5539100 Organic Solid State Switches Incorporating Porphyrin Compounds and Method for Producing Organic Solid State Optical Switches”, M. R. Wasielewski, G. L. Gaines III, M. P. Niemczyk, D. G. Johnson, D. J. Gosztola, and M. P. O’Neil